Journal of Advanced Chemical Engineering

The Realization of Electrochimically Commandable Systems

5^th International Conference on Advances in Chemical Engineering & Technology

October 04-05, 2018 | London, UK

Chahrazed Benhaoua, Mazari Mohamed, Yebedri Okacha, Le Derf Franck, M. Salle and A. Derdour

Laboratoire d’Ingenierie Moleculaire et Materiaux Organiques UMR CNRS 6501, Universite d’Angers, 2 Bd Lavoisier 49045 Angers Cedex, France Laboratoire de Synthese Organique Appliquee, Universite d’Oran Es-Senia, BP. 1524, Oran, Algeria. Departement Physique, Faculte des Sciences de la Matiere, Universite de Tiaret

Posters & Accepted Abstracts: J Adv Chem Eng

Abstract:

Several studies were carried out to develop molecular systems electrochemically controllable capable of modulating the complexation of some metal cations Our work was directed to the synthesis of new organic materials using the tetrathiafulvalene (TTF) as redox unit and propertied of polynitrogen spacer arms (podants) as an acceptor of the cationic species. Podants are acyclic agents with a pseudocavity constituted by complexing arms of various lengths having a high conformational flexibility. Our synthesized podants are nitrogenous derivatives containing a redox unit and tend to coordinner transition metal ions. In order to study for the complexassion transition elements (Ni 2+, Cd2 +, Co2 + Cr 2+), we chose the cyclic voltammetry, One of our compounds had a suitable structure and gave better recognition.