Journal of Petroleum & Environmental Biotechnology

Asphaltene and wax precipitation - Common principles of structuring

2^nd World Congress on Petroleum and Refinery

June 01-03, 2017 Osaka, Japan

Hartmut R Fischer

TNO Technical Sciences �?? The Netherlands

Keynote: J Pet Environ Biotechnol

Abstract:

Asphaltenes are a complex mixture of different molecules with similar chemical characteristics which are insoluble in aliphatic solvents (e.g. heptane) but soluble in aromatic ones (e.g. toluene). However, being also known as the �??cholesterol�?? of crude oil, they precipitate, adhere to surfaces and, in the worst cases, cause costly pipe blockages and alter the wetting characteristics of mineral surfaces within the reservoir, hindering oil recovery efficiency. Similar effects are also observed with respect to waxes. Even at very low concentrations in �??good�?? solvents, both still have a strong tendency to form nanoaggregates or nanocrystallites which transfer to micro- and macroaggregates whose structure and formation remain largely unknown despite much research. Aggregation proceeds from specific strong interaction sites located at the periphery of the asphaltene molecules. They drive the reversible association in two-dimensional sheets, a morphology which is consistent with reported scattering and viscosity data. Precipitation eventually occurs, determined by van der Waals attractions between aggregates, when the solubility parameter of the solvent is shifted. In our current research, we have focused on the several steps to tackle this problem which can heavily impact the economic value of a project, especially in harsh sub-sea environments, where deposition can halt production altogether. For example, intervention costs for asphaltene removal for a land-based well up to $0.5 MM US translates to more than $3 MM US for off-shore well production, and the economic loss as a result of lost/delayed production can amount to $1.2 MM US per day. The ability to predict the occurrence and magnitude of asphaltene deposition in wellbores is critical to forecast the related flow assurance challenges for deep and ultradeep water production. We therefore have the goal to find a solution (chemical, mechanical or otherwise) namely to: a) Understand the issues and help characterize the problem, b) Prevent or inhibit deposition (asphaltene alone or in combination with calcite) that interferes with production flow, and c) Manage or remediate deposits.

Biography :

Hartmut R Fischer is a Senior Research Scientist in TNO Technical Sciences and monitors materials’ performance and as such connected with all kinds of materials, their testing and evaluation with a focus on materials under extreme environments and the high end equipment applications. His areas of current activities are the assessment of pavement durability as well as adhesion and surface studies, the study and design of self-healing systems, the investigation and understanding of the micro structure of building materials leading to the design of modern building materials for applications under extreme circumstances. He acts as co-Promoter for PhD students and Mentor of Post-Docs at the TU Eindhoven and Delft in the areas polymer nanocomposites, self-healing systems and transport in porous media. He is also a referee for the German and Dutch Research Council as well as for about 40 scientific journals. He has authored 185 refereed publications, 35 patents and 8 book chapters.

Email: hartmut.fischer@tno.nl